Griesbeck, Axel G. and Diaz-Miara, Yrene and Fichtler, Robert and Jacobi von Wangelin, Axel and Perez-Ruiz, Raul and Sampedro, Diego (2015) Steric Enhancement of the Chemiluminescence of Luminols. CHEMISTRY-A EUROPEAN JOURNAL, 21 (28). pp. 9975-9979. ISSN 0947-6539, 1521-3765
Full text not available from this repository. (Request a copy)Abstract
A surprising 20-fold increase in chemiluminescence efficiency was observed for dialkyl luminol derivatives in comparison with the parent compound. This effect could be a direct consequence of steric gearing which facilitates the transition from the intermediate endoperoxide to the electronically excited phthalate. Mechanistic aspects of this process have been supported by computational calculations (CASPT2//CASSCF).
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ELECTROGENERATED CHEMILUMINESCENCE; HYDRAZIDES; DENSITY; BIOLUMINESCENCE; ALDEHYDES; SYSTEM; NANOPARTICLES; DERIVATIVES; DIENOPHILES; CHEMISTRY; ab initio calculations; chemiluminescence; conical intersections; luminols; steric gearing |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 08 Jul 2019 06:08 |
| Last Modified: | 08 Jul 2019 06:08 |
| URI: | https://pred.uni-regensburg.de/id/eprint/5214 |
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