Investigations of hard elastic polypropylene with respect to the coil-strand-transition model

Kreitmeier, Stefan and Wittkop, Markus and Wagner, T. and Göritz, Dietmar and Zietz, R. (1995) Investigations of hard elastic polypropylene with respect to the coil-strand-transition model. COLLOID AND POLYMER SCIENCE, 273 (11). pp. 1008-1021. ISSN 0303-402X, 1435-1536

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Abstract

Hard elastic polypropylene was investigated by x-ray scattering using synchrotron radiation and by performing stress strain measurements in different liquids. It was found that the long period increases with elongation up to lambda approximate to 1.3-1.4. Beyond this extension a change in the deformation behavior takes place. In the range from lambda approximate to 1.1 to lambda approximate to 1.3-1.4 the deformation measurements in the different liquids are in good agreement with the coil-strand-transition model. The proposed linear relationship between the deformation work and the elongation could be confirmed. The same holds for the surface energy. Moreover, the calculated ratio between the surface energy and the deformation work agrees with the measurements.

Item Type: Article
Uncontrolled Keywords: INTERNAL-FRICTION; GLASSY-POLYMERS; DEFORMATION; POLYETHYLENE; HARD ELASTIC POLYMERS; X-RAY SCATTERING; DEFORMATION BEHAVIOR; LIQUIDS; SURFACE TENSION; INHOMOGENEOUS DEFORMATION
Subjects: 500 Science > 530 Physics
Divisions: Physics > Institute of Experimental and Applied Physics > Alumni or Retired Professors > Group Dietmar Göritz
Depositing User: Dr. Gernot Deinzer
Date Deposited: 22 Dec 2023 08:04
Last Modified: 22 Dec 2023 08:04
URI: https://pred.uni-regensburg.de/id/eprint/52222

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