1,8-DISUBSTITUTED NAPHTHALENES BY DIRECTED METALATION AND SUBSEQUENT LITHIUM-MANGANESE EXCHANGE, INCLUDING COPPER CATALYSIS

KIEFL, C and MANNSCHRECK, A (1995) 1,8-DISUBSTITUTED NAPHTHALENES BY DIRECTED METALATION AND SUBSEQUENT LITHIUM-MANGANESE EXCHANGE, INCLUDING COPPER CATALYSIS. SYNTHESIS-STUTTGART (8). pp. 1033-1037. ISSN 0039-7881,

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Abstract

Directed lithiation of 1-dimethylamino- and 1-methoxynaphthalene, followed by Li-Mn exchange and reaction with electrophiles, provides regioselective syntheses of previously unknown racemic thioamides 2, 11 and 12, and ketones 5-8.

Item Type: Article
Uncontrolled Keywords: CARBOXYLIC-ACID CHLORIDES; ORGANOMANGANESE(II) REAGENTS; REACTIVITY; ACYLATION;
Depositing User: Dr. Gernot Deinzer
Last Modified: 19 Oct 2022 08:37
URI: https://pred.uni-regensburg.de/id/eprint/52419

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