KUNKELY, H and VOGLER, A (1995) PHOTOCHEMISTRY OF AQUEOUS TETRATHIOANTIMONATE(V). ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 50 (8). pp. 1155-1157. ISSN 0932-0776,
Full text not available from this repository.Abstract
The electronic spectrum of [SbS4](3-) in 10(-3) M NaOH displays an absorption band at lambda(max) = 285 nm which is assigned to a ligand-to-metal charge transfer (LMCT) transition. Upon LMCT excitation [SbS4](3-) undergoes an intramolecular redox reaction with the formation of [SbS3](3-) and elemental sulfur (phi = 0.11 at lambda(irr) = 333 nm).
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | MAIN GROUP-METALS; COORDINATION-COMPOUNDS; TIN; ANTIMONY(V); THIO COMPLEXES; ELECTRONIC SPECTRA; PHOTOCHEMISTRY |
| Depositing User: | Dr. Gernot Deinzer |
| Last Modified: | 19 Oct 2022 08:37 |
| URI: | https://pred.uni-regensburg.de/id/eprint/52420 |
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