PAWLOWSKI, V and KUNKELY, H and VOGLER, A (1995) PHOTOCHEMICAL GENERATION OF TRIBROMOSTANNATE(II) BY REDOX AND SUBSTITUTION-REACTIONS. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 50 (7). pp. 1035-1037. ISSN 0932-0776,
Full text not available from this repository.Abstract
Hexabromostannate(IV) in acetonitrile undergoes a photochemical reductive elimination according to the equation [SnBr6](2-) --> [SnBr3](-) + Br-3(-) with phi = 0.06 at lambda(irr) = 313 nm. The formation of [SnBr3](-) takes place also by irradiation of [Ru(SnBr3)(5)Br](4-) in acetonitrile with visible light. This photosubstitution occures with phi > 0.09 at lambda(irr) = 436 nm.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | MAIN GROUP-METALS; COORDINATION-COMPOUNDS; TIN(II); BROMO COMPLEXES; PHOTOCHEMISTRY |
| Depositing User: | Dr. Gernot Deinzer |
| Last Modified: | 19 Oct 2022 08:37 |
| URI: | https://pred.uni-regensburg.de/id/eprint/52477 |
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