Coupling electrochemistry to capillary electrophoresis-mass spectrometry

Cindric, Marija and Matysik, Frank-Michael (2015) Coupling electrochemistry to capillary electrophoresis-mass spectrometry. TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 70. pp. 122-127. ISSN 0165-9936, 1879-3142

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Abstract

Hyphenated techniques have become an important tool in modern analytical research. Among detection techniques, mass spectrometry (MS) plays a dominant role, but efficient analyte separation prior to MS detection is usually desirable, as it provides the basis for reliable qualitative and quantitative determination. However, electrochemical methods offer very versatile approaches for selective sample pretreatment or analyte conversion. This review summarizes recent instrumental analytical developments, which resulted in a special kind of a hyphenated system: electrochemistry-capillary electrophoresis-MS (EC-CE-MS). We discuss the analytical characteristics of this approach and compare them with those of other techniques coupling EC with separation techniques and MS. (C) 2015 Elsevier B.V. All rights reserved.

Item Type: Article
Uncontrolled Keywords: CONTACTLESS CONDUCTIVITY DETECTION; QUINONE ANION-RADICALS; ASSISTED INJECTION; SEPARATION; QUANTIFICATION; DERIVATIZATION; COMBINATION; INTERFACE; PRODUCTS; Analytical characteristic; Capillary electrophoresis; Coupling; EC-CE-MS; Electrochemical flow cell; Electrochemistry; Electrochemically-assisted injection; Mass spectrometry; Neutral compound; Screen-printed electrode
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Analytische Chemie, Chemo- und Biosensorik > Instrumentelle Analytik (Prof. Frank-Michael Matysik)
Depositing User: Petra Gürster
Date Deposited: 21 Aug 2020 11:49
Last Modified: 21 Aug 2020 11:49
URI: https://pred.uni-regensburg.de/id/eprint/5261

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