BRUNNER, H and NET, G (1995) ENANTIOSELECTIVE CATALYSIS .93. OPTICALLY-ACTIVE EXPANDED PHOSPHANES DERIVED FROM 1,2-BISPHOSPHANOBENZENE AND AMIDES AND ESTERS OF ACRYLIC-ACID. SYNTHESIS-STUTTGART (4). pp. 423-426. ISSN 0039-7881,
Full text not available from this repository.Abstract
Three new expanded phosphanes were synthesized by reaction of 1,2-bisphosphanobenzene with optically active derivatives of acrylic acid: (R)-(+)-N-methyl-N-(1-phenethyl)acrylamide, (1S,2R,5S)-(+)-menthyl acrylate and (1S)-endo-(-)-bornyl acrylate. The three phosphanes with [Rh-2(mu-Cl)(2)(COD)(2)] as in situ catalysts, as well as the isolated complexes [Rh(PP)(COD)]PF6, where PP and COD denote a phosphane and 1,5-cyclooctadiene, respectively, were tested in several enantioselective catalytic reactions.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ASYMMETRIC ALLYLIC ALKYLATION; HYDROGENATION; LIGANDS; PHOSPHINES; COMPLEXES; OLEFINS; EXPANDED OPTICALLY ACTIVE PHOSPHANES; P-H ADDITION TO DOUBLE BONDS; ENANTIOSELECTIVE TRANSITION-METAL CATALYSIS |
| Depositing User: | Dr. Gernot Deinzer |
| Last Modified: | 19 Oct 2022 08:38 |
| URI: | https://pred.uni-regensburg.de/id/eprint/52676 |
Actions (login required)
 |
View Item |
