KUNKELY, H and VOGLER, A (1994) PHOTOCHEMISTRY OF THE OXO-BRIDGED DIIRON(III) CORE - EVOLUTION OF OXYGEN-INDUCED BY FE-III TO FE-III CHARGE-TRANSFER EXCITATION OF MU-OXOBIS[(ETHYLENEDIAMINETETRAACETATO)FERRATE(III)]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS (23). pp. 2671-2672. ISSN 0022-4936,
Full text not available from this repository.Abstract
The reversible photolysis of aqueous [{Fe-III(edta)}O-2](4-) leads to the evolution of oxygen and the formation of [Fe-II(edta)](2-); it is suggested that the photoreaction is induced by Fe-III to Fe-III charge-transfer excitation, which yields Fe-II and Fe-IV=0 in the primary photochemical step.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ELECTRONIC-STRUCTURE; IRON-OXO; COMPLEXES; WATER; CHEMISTRY; BIOLOGY; SITES; |
| Depositing User: | Dr. Gernot Deinzer |
| Last Modified: | 19 Oct 2022 08:39 |
| URI: | https://pred.uni-regensburg.de/id/eprint/52926 |
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