CHHIH, A and TURQ, P and BERNARD, O and BARTHEL, JMG and BLUM, L (1994) TRANSPORT-COEFFICIENTS AND APPARENT CHARGES OF CONCENTRATED ELECTROLYTE-SOLUTIONS - EQUATIONS FOR PRACTICAL USE. BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 98 (12). pp. 1516-1525. ISSN 0005-9021,
Full text not available from this repository.Abstract
Simple expressions for the transport coefficient in the mean spherical approximation (MSA) have been derived. We study the self-diffusion, conductance and apparent charge of simple electrolytes, where we find good agreement for the concentration dependence. Associated electrolytes are also well described by a natural extension of this theory. The MSA equations extend the concentration range of the chemical model (CM) calculations which, in turn, are a reliable source for the input parameters of the MSA calculations.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | MEAN SPHERICAL APPROXIMATION; SELF-DIFFUSION; ASYMMETRIC ELECTROLYTES; ION-ASSOCIATION; CONDUCTANCE; ACETONITRILE; THERMODYNAMICS; DEPENDENCE; CALCIUM; MODEL; DIFFUSION; ELECTROLYTE CONDUCTIVITY; ELECTROLYTE SOLUTIONS; STATISTICAL MECHANICS; TRANSPORT PROPERTIES |
| Depositing User: | Dr. Gernot Deinzer |
| Last Modified: | 19 Oct 2022 08:39 |
| URI: | https://pred.uni-regensburg.de/id/eprint/52933 |
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