BULGAREVICH, SB and VANOVA, NA and MOVSHOVICH, DY and MANNSCHRECK, A and KIEFL, C (1994) CONFORMATIONAL INVESTIGATION OF 1,8-DISUBSTITUTED NAPHTHALENES AS SOLUTES BY KERR-EFFECT AND DIPOLE-MOMENT METHODS. JOURNAL OF MOLECULAR STRUCTURE, 326. pp. 17-24. ISSN 0022-2860,
Full text not available from this repository.Abstract
Molar Kerr constants and electric dipole moments are reported for 1-methoxycarbonylnaphthalene, 1-bromo-5-methoxycarbonylnaphthalene, 1-bromo-5-nitronaphthalene, 1-amino-8-bromonaphthalene, 1-dimethylamino-8-methoxycarbonylnaphthalene and 1-dimethylamino-8-dimethylthiocarbamoylnaphthalene as solutes in dioxane at 298 K. The data are analyzed in terms of the preferred conformations in solution. These data are consistent with acoplanar orientations of 1- and 1,8-substituents relative to the naphthalene plane. The preferred conformers of the last two molecules are stabilized by a Me2N...C=O(S) through-space interaction.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ; |
| Depositing User: | Dr. Gernot Deinzer |
| Last Modified: | 19 Oct 2022 08:39 |
| URI: | https://pred.uni-regensburg.de/id/eprint/53076 |
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