PHOTOLUMINESCENCE OF TETRACHLOROARSENATE(III)

KUNKELY, H and PAWLOWSKI, V and VOGLER, A (1994) PHOTOLUMINESCENCE OF TETRACHLOROARSENATE(III). CHEMICAL PHYSICS LETTERS, 227 (3). pp. 267-269. ISSN 0009-2614,

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Abstract

Glasses of (NBu4)AsCl4 in ethanolal 77 K show a red emission at lambda(max) = 617 nm with phi almost-equal-to 10(-4) and tau = 0.46 mus. It is suggested that this luminescence originates from the sp excited state P-3(1) of the As3+ ion. The excited state properties of AsCl4- are discussed in comparison to those of SbCl4- and BiCl4-.

Item Type: Article
Uncontrolled Keywords: ANTIMONY(III); LUMINESCENCE; COMPLEXES;
Depositing User: Dr. Gernot Deinzer
Last Modified: 19 Oct 2022 08:39
URI: https://pred.uni-regensburg.de/id/eprint/53083

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