Desat, Marcella E. and Gaertner, Stefanie and Kretschmer, Robert (2017) Dinuclear indium and thallium diyls: biscarbenoids or metal cluster? CHEMICAL COMMUNICATIONS, 53 (9). pp. 1510-1513. ISSN 1359-7345, 1364-548X
Full text not available from this repository. (Request a copy)Abstract
Using bis(beta-diketiminate) ligands we were able to synthesize unprecedented indium and thallium biscarbenoids. For indium, a novel four-membered metallacycle is derived from intra-and intermolecular In-In interactions in the solid state, while for thallium only an intramolecular Tl-2-pseudo-dimer is obtained. Computational studies revealed that the solid-state structures benefit significantly from dispersion stabilization.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CARBENE ANALOG; STRUCTURAL-CHARACTERIZATION; BETA-DIKETIMINATO; LONDON DISPERSION; SOLID-STATE; COMPLEXES; COMPOUND; GALLIUM; CHEMISTRY; ELEMENTS; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Dr. Robert Kretschmer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 14 Dec 2018 13:01 |
| Last Modified: | 26 Feb 2019 07:27 |
| URI: | https://pred.uni-regensburg.de/id/eprint/531 |
Actions (login required)
 |
View Item |
