Visible Light-Mediated Metal-Free Synthesis of Vinyl Sulfones from Aryl Sulfinates

Meyer, Andreas Uwe and Jaeger, Stefanie and Hari, Durga Prasad and Koenig, Burkhard (2015) Visible Light-Mediated Metal-Free Synthesis of Vinyl Sulfones from Aryl Sulfinates. ADVANCED SYNTHESIS & CATALYSIS, 357 (9). pp. 2050-2054. ISSN 1615-4150, 1615-4169

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Abstract

Visible light and eosin Y catalyze the synthesis of vinyl sulfones from aryl sulfinates and alkenes by a photoredox process. The reaction scope is broad in aryl sulfinates and alkenes and the general and simple procedure provides a metal-free alternative for the synthesis of synthetically valuable vinyl sulfones.

Item Type: Article
Uncontrolled Keywords: CYSTEINE PROTEASE INHIBITORS; C-H FUNCTIONALIZATION; AEROBIC OXYSULFONYLATION; (E)-ALKENYL SULFONES; PHOTOREDOX CATALYSIS; ASYMMETRIC-SYNTHESIS; ALKENES; ALKYNES; ACIDS; PHOSPHONATES; aryl sulfinates; metal-free conditions; photocatalysis; vinyl sulfones; visible light
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Depositing User: Dr. Gernot Deinzer
Date Deposited: 10 Jul 2019 14:03
Last Modified: 10 Jul 2019 14:03
URI: https://pred.uni-regensburg.de/id/eprint/5315

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