ASYMMETRIC CATALYSIS .86. ENANTIOSELECTIVE EPOXIDATION OF N-ALLYLTRICHLOROACETAMIDE WITH TERT-BUTYLHYDROPEROXIDE AND MO-DOTED Y-ZEOLITES, SILICA-GEL, AS WELL AS ISOPROPYL TARTRATE

BRUNNER, H and STUMPF, A (1994) ASYMMETRIC CATALYSIS .86. ENANTIOSELECTIVE EPOXIDATION OF N-ALLYLTRICHLOROACETAMIDE WITH TERT-BUTYLHYDROPEROXIDE AND MO-DOTED Y-ZEOLITES, SILICA-GEL, AS WELL AS ISOPROPYL TARTRATE. MONATSHEFTE FUR CHEMIE, 125 (5). pp. 485-489. ISSN 0026-9247,

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Abstract

N-Allyl-trichloroacetamide was epoxidized with tert-butylhydroperoxide in toluene to give N-2,3-(epoxypropyl)trichloroacetamide with an enantiomeric excess of up to 43% ee. The enantioselective heterogeneous catalysts used were Mo-doted Y-zeolites and silicagel modified with 2R,3R-(+)-isopropyl tartrate.

Item Type: Article
Uncontrolled Keywords: ; EPOXIDATION; ENANTIOSELECTIVITY; N-ALLYLTRICHLOROACETAMIDE DERIVATIVES; ISOPROPYL TARTRATE; MO-DOTED Y-ZEOLITES
Depositing User: Dr. Gernot Deinzer
Last Modified: 19 Oct 2022 08:40
URI: https://pred.uni-regensburg.de/id/eprint/53306

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