REFINEMENT OF THE CRYSTAL-STRUCTURE OF SRO2

RANGE, KJ and RAU, F and SCHIESSL, U and KLEMENT, U (1994) REFINEMENT OF THE CRYSTAL-STRUCTURE OF SRO2. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 620 (5). pp. 879-881. ISSN 0044-2313,

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Abstract

Single crystals of SrO2 have been obtained after high pressure/high temperature reaction of a SrO/KClO3 mixture at 20 kbar, 1400-degrees-C. The crystal structure was refined using 154 unique diffractometer data (I4/mmm; a = 3.5626(3), c = 6.6159(6) angstrom; Z = 2; R = 0.033, R(w) = 0.022, S = 0.932). The O-O distance (1.493(4) angstrom) is significantly longer than the one previously assumed. From a refinement of the site occupation factor for oxygen a composition SrO1.95(2) has been found for the crystal investigated.

Item Type: Article
Uncontrolled Keywords: NEODYMIUM(III) OXIDE PEROXIDE; ND2O2(O2); STRONTIUM PEROXIDE; CRYSTAL STRUCTURE; COMPOSITION
Depositing User: Dr. Gernot Deinzer
Last Modified: 19 Oct 2022 08:40
URI: https://pred.uni-regensburg.de/id/eprint/53314

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