KRITZENBERGER, J and YERSIN, H and RANGE, KJ and ZABEL, M (1994) CRYSTAL-STRUCTURE OF TRANS-BIS(ACETONITRILE)DICHLOROPLATINUM(II). ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 49 (3). pp. 297-300. ISSN 0932-0776,
Full text not available from this repository.Abstract
We have determined the crystal and molecular structure of trans-bis(acetonitrile)dichloroplatinum(II). Crystallographic data for trans-Pt(CH3CN)(2)Cl-2: monoclinic, space group P2(1)/c, a = 5.0453(9), b = 6.9896(5), c = 11.962(1) Angstrom, beta = 101.40(1)degrees, V = 413.5 Angstrom(3), Z = 2, D-x = 2.796 gcm(-3), mu(CuK alpha) = 377.5 cm(-1), R = 0.0502, wR = 0.0529 for 43 variables and 807 reflections with F > 3 sigma(F). The Pt atom is in a planar configuration with N and Cl atoms in trans positions. The shortest distance between two Pt atoms corresponds to the length of the crystallographic a-axis (5.045 Angstrom). Additionally, we present optical absorption data of the cis- and trans-isomer.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | BIS(ACETONITRILE)DICHLOROPLATINUM(II); ISOMERS; CIS; CRYSTAL STRUCTURE; ABSORPTION DATA; TRANS-BIS(ACETONITRILE) DICHLOROPLATINUM(II) |
| Depositing User: | Dr. Gernot Deinzer |
| Last Modified: | 19 Oct 2022 08:40 |
| URI: | https://pred.uni-regensburg.de/id/eprint/53451 |
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