BREU, J and RANGE, KJ (1994) CHIRAL RECOGNITION AMONG TRISDIIMINE-METAL COMPLEXES .3. ADSORPTION OF TRIS-(3,3'-BI-1,2,4-TRIAZINE)IRON(II) COMPLEXES ONTO MONTMORILLONITE. MONATSHEFTE FUR CHEMIE, 125 (2). pp. 153-165. ISSN 0026-9247,
Full text not available from this repository.Abstract
Adsorption isotherms of tris-(3,3'-bi-1,2,4-triazine)iron(II) complexes onto a well characterized montmorillonite are discussed in respect to the relative charge densities of adsorbent and adsorbat. While the adsorption capacities for trisbipyridyl and trisphenanthroline complexes differ for the racemates and the enantiomers they are equal for these complexes. Adsorption is limited to a monolayer. This backs the proposal that the observed chiral recognition phenomena are founded solely in the lateral interactions between adsorbats.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | X-RAY-DIFFRACTION; OPTICAL RESOLUTION; COLLOIDAL CLAY; VERMICULITE; INTERCALATE; DICHROISM; SILICATES; HECTORITE; FILMS; CHIRAL RECOGNITION; CHIRAL DISCRIMINATION; SMECTITE; CLAY MINERALS; SURFACE CHARGE; INTERCALATION; ADSORPTION CAPACITIES; DIFFRACTION PATTERNS; TRISDIIMINE COMPLEXES |
| Depositing User: | Dr. Gernot Deinzer |
| Last Modified: | 19 Oct 2022 08:41 |
| URI: | https://pred.uni-regensburg.de/id/eprint/53489 |
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