DIENOPHILIC REACTIVITY OF PENTACARBONYL(METHOXYVINYLCARBENE)TUNGSTEN IN (4+2)-CYCLOADDITIONS

ADAM, H and ALBRECHT, T and SAUER, J (1994) DIENOPHILIC REACTIVITY OF PENTACARBONYL(METHOXYVINYLCARBENE)TUNGSTEN IN (4+2)-CYCLOADDITIONS. TETRAHEDRON LETTERS, 35 (4). pp. 557-560. ISSN 0040-4039,

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Abstract

The vinyl-methoxy-carbene complex 1 shows dienophilic reactivity comparable to maleic anhydride in (4+2)-cycloadditions. The reactions of 1 with unsymmetrical 1,3-dienes are stereo- and regioselective.

Item Type: Article
Uncontrolled Keywords: DIELS-ALDER REACTIONS; CARBENE COMPLEXES;
Depositing User: Dr. Gernot Deinzer
Last Modified: 19 Oct 2022 08:41
URI: https://pred.uni-regensburg.de/id/eprint/53506

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