GOLD-ALKALI METAL-SYSTEMS .3. HIGH-PRESSURE SYNTHESIS AND CRYSTAL-STRUCTURE OF RB3AU7

RANGE, KJ and GROSCH, GH and RAU, F and KLEMENT, U (1994) GOLD-ALKALI METAL-SYSTEMS .3. HIGH-PRESSURE SYNTHESIS AND CRYSTAL-STRUCTURE OF RB3AU7. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 49 (1). pp. 27-30. ISSN 0932-0776,

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Abstract

The intermetallic compound Rb3Au7 could be synthesized from the elements at 4 kbar, 700 degrees C in a modified Belt-type apparatus. The structure (Cmmm; a = 5.579(1), b = 13.267(5), c = 7.265(2)Angstrom; Z = 2; R = 0.035, R(w) = 0,031) comprises three crystallographically independent Au Atoms, arranged in layers along the c-axis. The shortest interatomic distances are Au-Au = 2.633 Angstrom, Au-Rb = 3.438 Angstrom and Rb- Rb = 3.622 Angstrom.

Item Type: Article
Uncontrolled Keywords: ; TRIRUBIDIUM HEPTAGOLD; HIGH PRESSURE SYNTHESIS; CRYSTAL STRUCTURE
Depositing User: Dr. Gernot Deinzer
Last Modified: 19 Oct 2022 08:41
URI: https://pred.uni-regensburg.de/id/eprint/53612

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