KUNKELY, H and VOGLER, A (1993) PHOTOCHEMISTRY OF CYCLOPENTADIENYLTHALLIUM(I). JOURNAL OF ORGANOMETALLIC CHEMISTRY, 459 (1-2). pp. 21-23. ISSN 0022-328X, 1872-8561
Full text not available from this repository.Abstract
TlC5H5 displays absorption maxima at 228 and 280 nm which are assigned to metal-centred sp and ligand-to-metal charge transfer (LMCT) transitions, respectively. The complex shows an emission at lambda(max) = 360 nm which originates from a low-energy sp excited state. The photolysis of TlC5H5 in methanol proceeds according to the equation TlC5H5 + CH3OH --> TlOH + H-2 + C6H6 (pentafulvene) with phi = 0.1 at lambda(irr) = 254 nm and 0.008 at 313 nm. It is suggested that this photoreaction is induced by LMCT excitation.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | MAIN-GROUP ELEMENTS; COMPLEXES; DEHYDRODIMERIZATION; |
| Depositing User: | Dr. Gernot Deinzer |
| Last Modified: | 19 Oct 2022 08:42 |
| URI: | https://pred.uni-regensburg.de/id/eprint/53712 |
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