THE 1ST NEUTRAL ADAMANTANOID IRON(III)-CHELATE COMPLEX - SPONTANEOUS FORMATION, STRUCTURE, AND ELECTROCHEMISTRY

SAALFRANK, RW and HORNER, B and STALKE, D and SALBECK, J (1993) THE 1ST NEUTRAL ADAMANTANOID IRON(III)-CHELATE COMPLEX - SPONTANEOUS FORMATION, STRUCTURE, AND ELECTROCHEMISTRY. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 32 (8). pp. 1179-1182. ISSN 0570-0833,

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Abstract

''Metalloautism''-this term perfectly describes the characteristic of the adamantanoid iron(III) chelate complex 1 that the four iron centers do not interact with each other either electronically or magnetically. The four metal atoms are linked by six chelatino ligands (2), which are prepared by deprotonation of the product of the condensation of terephthaloyl chloride and dimethyl malonate.

Item Type: Article
Uncontrolled Keywords: ELECTRON-TRANSFER REACTIONS; SUPRAMOLECULAR CHEMISTRY; DESULFOVIBRIO-VULGARIS; CYCLIC VOLTAMMETRY; CHELATE COMPLEXES; 2-ELECTRON; MOLECULES; BINUCLEAR; TRIETHYLAMINE; CYTOCHROME-C3;
Depositing User: Dr. Gernot Deinzer
Last Modified: 19 Oct 2022 08:42
URI: https://pred.uni-regensburg.de/id/eprint/53837

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