SHAKERGAAFAR, N and KARGER, N and WAPPMANN, S and LUDEMANN, HD (1993) P, T-DEPENDENCE OF SELF-DIFFUSION IN LIQUID ETHANOL AND THE PROPANOLS. BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 97 (6). pp. 805-811. ISSN 0005-9021,
Full text not available from this repository.Abstract
The p, T-dependence of the self diffusion coefficients D for ethanol-OD, 1 - and 2-propanol-OH and -OD have been studied in a wide temperature range at pressures up to 200 MPa. The experiments were performed in strengthened high pressure glass cells by the pulsed field gradient NMR-technique. The isobaric temperature dependence of D is given by the VTF-equation. The isotherms can be fitted to the rough hard sphere model with an A-parameter that decreases strongly with falling temperature.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | MONOHYDRIC ALCOHOLS; HEAVY-WATER; PRESSURE; DIFFUSION; HIGH PRESSURE; ISOTOPE EFFECTS; LIQUIDS; SPECTROSCOPY, NUCLEAR MAGNETIC RESONANCE |
| Depositing User: | Dr. Gernot Deinzer |
| Last Modified: | 19 Oct 2022 08:42 |
| URI: | https://pred.uni-regensburg.de/id/eprint/53929 |
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