REACTIVITY STUDIES ON TANTALOCENE(SULFIDO)HYDRIDE CP'2TA(=S)H (CP' = BU(T)C5H4) - CYCLOADDITION ON AND PROTONATION OF THE TA=S LIGAND

BRUNNER, H and KUBICKI, MM and LEBLANC, JC and MOISE, C and VOLPATO, F and WACHTER, J (1993) REACTIVITY STUDIES ON TANTALOCENE(SULFIDO)HYDRIDE CP'2TA(=S)H (CP' = BU(T)C5H4) - CYCLOADDITION ON AND PROTONATION OF THE TA=S LIGAND. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS (10). pp. 851-852. ISSN 0022-4936,

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Abstract

Reactions of the tantalocene(sulfido)hydride Cp'2Ta(=S)H with PhNCS and HCl exhibit a surprisingly low metal-hydride reactivity; the Ta=S bond being involved either in a [2 + 2] cycloaddition or a protonation.

Item Type: Article
Uncontrolled Keywords: INSERTION; BOND;
Depositing User: Dr. Gernot Deinzer
Last Modified: 19 Oct 2022 08:42
URI: https://pred.uni-regensburg.de/id/eprint/53955

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