PHOTOLUMINESCENCE OF A TRIANGULAR HG-3(4+) CLUSTER

KUNKELY, H and VOGLER, A (1993) PHOTOLUMINESCENCE OF A TRIANGULAR HG-3(4+) CLUSTER. CHEMICAL PHYSICS LETTERS, 206 (5-6). pp. 467-469. ISSN 0009-2614,

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Abstract

The cluster compound Hg3(mu-dppm)3(SO4)2 (dppm = diphenylphosphinomethane) which contains the triangular Hg-3(4+) moiety shows an intense low-temperature (77 K) photoluminescence at lambda(max) = 658 nm. This emission is assumed to originate from a metal-centered ss excited state which undergoes a Jahn-Teller distortion.

Item Type: Article
Uncontrolled Keywords: COMPLEXES;
Depositing User: Dr. Gernot Deinzer
Last Modified: 19 Oct 2022 08:42
URI: https://pred.uni-regensburg.de/id/eprint/53963

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