CO2 ACTIVATION .2. [(PP)2RHH] AND [(PP)2RH][O2CH] COMPLEXES AS MODELS FOR THE CATALYTICALLY ACTIVE INTERMEDIATES IN THE RH-CATALYZED HYDROGENATION OF CO2 TO HCOOH

BURGEMEISTER, T and KASTNER, F and LEITNER, W (1993) CO2 ACTIVATION .2. [(PP)2RHH] AND [(PP)2RH][O2CH] COMPLEXES AS MODELS FOR THE CATALYTICALLY ACTIVE INTERMEDIATES IN THE RH-CATALYZED HYDROGENATION OF CO2 TO HCOOH. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 32 (5). pp. 739-741. ISSN 0570-0833,

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Abstract

The insertion of CO2 into the Rh-H bond of neutral hydrido complexes to form ionic complexes of type 1 now appears to be the key step in the title reaction. All intermediates were either isolated or detected by spectroscopy. The influence of the phosphane ligands on the reactivity of these model complexes is the same as their influence on the activity of the in situ catalysts normally used.

Item Type:	Article
Uncontrolled Keywords:	TRANSITION-METAL COMPLEXES; CARBON-DIOXIDE; RHODIUM; FORMATE; REACTIVITY; REDUCTION; DERIVATIVES;
Depositing User:	Dr. Gernot Deinzer
Last Modified:	19 Oct 2022 08:42
URI:	https://pred.uni-regensburg.de/id/eprint/53967

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