BRUNNER, H and KONIG, W and NUBER, B (1993) ENANTIOSELECTIVE CATALYSIS .83. SYNTHESIS OF OPTICALLY-ACTIVE FERROCENYLALANINE. TETRAHEDRON-ASYMMETRY, 4 (4). pp. 699-707. ISSN 0957-4166,
Full text not available from this repository.Abstract
Ferrocenylalanine, a possible substitute for phenylalanine in the commercial sweetener aspartame, was synthesized by asymmetric hydrogenation of the corresponding dehydro acylamino acids with rhodium/phosphine catalysts in up to 94% enantiomeric excess. The absolute configuration of N-benzoyl-ferrocenyl alanine 4 was determined by single-crystal X-ray analysis.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | HYDROGENATION; COMPLEXES; PEPTIDES; NORPHOS; ACID; |
| Depositing User: | Dr. Gernot Deinzer |
| Last Modified: | 19 Oct 2022 08:42 |
| URI: | https://pred.uni-regensburg.de/id/eprint/54045 |
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