ELECTRONIC-STRUCTURE AND SPECTROSCOPIC PROPERTIES OF COPPER CATECHOLATE COMPLEXES WITH INTERLIGAND CHARGE-TRANSFER BEHAVIOR

BENEDIX, R and VOGLER, A (1993) ELECTRONIC-STRUCTURE AND SPECTROSCOPIC PROPERTIES OF COPPER CATECHOLATE COMPLEXES WITH INTERLIGAND CHARGE-TRANSFER BEHAVIOR. INORGANICA CHIMICA ACTA, 204 (2). pp. 189-193. ISSN 0020-1693,

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Abstract

The structural and spectroscopic properties of copper catecholate complexes with nitrogen ligands of the alpha-diimine type are studied by qualitative MO considerations. The characteristic feature of these donor acceptor systems is an interligand charge-transfer from the catecholate donor to the alpha-diimine acceptor site. The dependence of the interligand charge-transfer absorption band on the energies of the acceptor and the donor levels as well as on the solvent polarity is discussed.

Item Type: Article
Uncontrolled Keywords: MIXED-LIGAND COMPLEXES; ALPHA-DIIMINE LIGANDS; CRYSTAL-STRUCTURE; TRANSFER ABSORPTION; OXALATE; SYSTEMS; AMINES; NICKEL;
Depositing User: Dr. Gernot Deinzer
Last Modified: 19 Oct 2022 08:43
URI: https://pred.uni-regensburg.de/id/eprint/54115

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