KARCHER, T and SICKING, W and SAUER, J and SUSTMANN, R (1992) SOLVENT EFFECTS ON ENDO/EXO SELECTIVITIES IN (4 + 2) CYCLOADDITIONS OF CYANOETHYLENES. TETRAHEDRON LETTERS, 33 (52). pp. 8027-8030. ISSN 0040-4039,
Full text not available from this repository.Abstract
SCRF calculations on transition structures of cycloadditions of acrylonitrile and maleonitrile to cyclopentadiene and 1,3-butadiene show that the experimentally observed endo preference for the cycloaddition of acrylonitrile to cyclopentadiene is the consequence of solvent influence and not the result of secondary orbital interactions.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | DIELS-ALDER REACTIONS; BUTADIENE; |
| Depositing User: | Dr. Gernot Deinzer |
| Last Modified: | 19 Oct 2022 08:44 |
| URI: | https://pred.uni-regensburg.de/id/eprint/54251 |
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