SALBECK, J and KOMISSAROV, VN and MINKIN, VI and DAUB, J (1992) MOLECULAR SWITCHING BY ELECTRON-TRANSFER - THE SPIROPERIMIDINE QUINONIMINE SYSTEM. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 31 (11). pp. 1498-1500. ISSN 1433-7851, 1521-3773
Full text not available from this repository.Abstract
The isomerization between spiroperimidine 1 and quinonimine 2 is reversibly switchable in a multistep process. The forward reaction takes place by electron transfer, while the reverse reaction is a thermal process. The intermediate radical anions and dianions were identified and the mechanism was elucidated.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CYCLIC VOLTAMMETRY; REARRANGEMENT; |
| Depositing User: | Dr. Gernot Deinzer |
| Last Modified: | 19 Oct 2022 08:44 |
| URI: | https://pred.uni-regensburg.de/id/eprint/54295 |
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