Photoluminescence of mixed-ligand metallacyclopentane diolefin or bipyridyl complexes. Emission from LLCT triplets under ambient conditions

Vogler, Arnd (2015) Photoluminescence of mixed-ligand metallacyclopentane diolefin or bipyridyl complexes. Emission from LLCT triplets under ambient conditions. INORGANIC CHEMISTRY COMMUNICATIONS, 56. pp. 87-88. ISSN 1387-7003, 1879-0259

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Abstract

The complexes Ir(III)(nbd(2)(2-))(L-L)(acetylacetonate) with nbd(2)(2-) = bis-norbornadienyl dianion and L-L = norbornadiene and 2,2'-bipyridyl and Pd(II)[C-4(COOMe)(4)](2,2'-bipyridyl) contain metallacycles and a diolefin or bipyridyl as additional ligand. These complexes are characterized by low-energy LLCT excited states. The CT donor site is associated with the metallacycle while the CT acceptor function is provided by a diolefin or bipy. The LLCT triplets are emissive in solution under ambient conditions. (C) 2015 Elsevier B.V. All rights reserved.

Item Type: Article
Uncontrolled Keywords: ; Luminescence; Metallacycle; Iridium(III); Palladium(II); LLCT; Triplet emitter
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Anorganische Chemie
Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler
Depositing User: Dr. Gernot Deinzer
Date Deposited: 15 Jul 2019 08:56
Last Modified: 15 Jul 2019 08:56
URI: https://pred.uni-regensburg.de/id/eprint/5440

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