BRUNNER, H and GEHART, G and NUBER, B and WACHTER, J and ZIEGLER, ML (1992) THE REACTION OF [CP2+NB2(B2H6)2] (CP+ = ETA-ETME4C5) WITH SULFUR - STABILIZATION OF THE TETRATHIOBORATO LIGAND IN NOVEL SULFIDO NIOBIUM CLUSTERS. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 31 (8). pp. 1021-1023. ISSN 0570-0833,
Full text not available from this repository.Abstract
An equilateral Nb3 triangle the edges of which are spanned by a BS4 tetrahedron and bridged by sulfido ligands on the "underside" is found in cluster 1. The synthesis of this cluster with an unusual electron configuration shows that tetrathioborates can serve as ligands in organometallic chemistry. Cp+ = eta-5-EtMe4C5.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | MAIN GROUP ELEMENTS; <(ETA-5-C5ME5)3RE3(MU-O)6>2+; |
| Depositing User: | Dr. Gernot Deinzer |
| Last Modified: | 19 Oct 2022 08:44 |
| URI: | https://pred.uni-regensburg.de/id/eprint/54431 |
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