NIKOL, H and BECHT, A and VOGLER, A (1992) PHOTOLUMINESCENCE OF GERMANIUM(II), TIN(II), AND LEAD(II) CHLORIDE COMPLEXES IN SOLUTION. INORGANIC CHEMISTRY, 31 (15). pp. 3277-3279. ISSN 0020-1669,
Full text not available from this repository.Abstract
The absorption and emission spectra of GeCl3-, SnCl3-, PbCl3-, and PbCl42- in acetonitrile were recorded. In addition, emission quantum yields and lifetimes were determined. The emitting excited states are of the metal-centered sp type and originate from the 3P State of the free s2 ions. It is suggested that the complex ions which have trigonal-pyramidal C3v (MC13-) and seesaw C2v (PbCl42-) structures in the ground state rearrange toward trigonal-planar D3h and tetrahedral T(d) geometries, respectively, in their sp excited states.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CRYSTAL-STRUCTURE; EXCITED-STATE; ANTIMONY(III); LUMINESCENCE; CHEMISTRY; IRIDIUM; |
| Depositing User: | Dr. Gernot Deinzer |
| Last Modified: | 19 Oct 2022 08:44 |
| URI: | https://pred.uni-regensburg.de/id/eprint/54458 |
Actions (login required)
 |
View Item |
