PHOTOLYSIS OF FE(CO)42- IN AN AQUEOUS NAOH GLASS AT 77 K - FORMATION OF SOLVATED ELECTRONS

KUNKELY, H and VOGLER, A (1992) PHOTOLYSIS OF FE(CO)42- IN AN AQUEOUS NAOH GLASS AT 77 K - FORMATION OF SOLVATED ELECTRONS. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 431 (3). C42-C44. ISSN 0022-328X,

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Abstract

The photolysis of [Fe(CO)4]2- in 10 M NaOH glass at 77 K leads to the formation of solvated electrons with theta = 0.03 at lambda(irr) = 254 nm. The solvated electrons, which are stable under these conditions, are identified by their characteristic absorption band at lambda(max) = 588 nm.

Item Type: Article
Uncontrolled Keywords: TRANSITION-METAL CARBONYLS; CR(CO)6;
Depositing User: Dr. Gernot Deinzer
Last Modified: 19 Oct 2022 08:44
URI: https://pred.uni-regensburg.de/id/eprint/54464

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