GRAF, E and LEITNER, W (1992) DIRECT FORMATION OF FORMIC-ACID FROM CARBON-DIOXIDE AND DIHYDROGEN USING THE [(RH(COD)CL)2]-PH2P(CH2)4PPH2 CATALYST SYSTEM. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS (8). pp. 623-624. ISSN 0022-4936,
Full text not available from this repository.Abstract
Formic acid, isolable as sodium formate from the reaction mixture, is produced directly from hydrogen and carbon dioxide with yields up to 1150 moles per mole of rhodium using a homogeneous catalyst formed in situ from [{Rh(cod)Cl}2] and Ph2P(CH2)4PPh2; the precious metal is recovered during work-up in a catalytically active form.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | TRANSITION-METAL COMPLEXES; ENANTIOSELECTIVE CATALYSIS; TRANSFER-HYDROGENATION; |
| Depositing User: | Dr. Gernot Deinzer |
| Last Modified: | 19 Oct 2022 08:44 |
| URI: | https://pred.uni-regensburg.de/id/eprint/54572 |
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