SEIDL, M and KAA, J and MAIER, M (1991) RELAXATION OF SINGLET MOLECULAR-OXYGEN IN THE LIQUID AND GAS-PHASE UP TO 154-K. CHEMICAL PHYSICS, 157 (1-2). pp. 279-285. ISSN 0301-0104, 1873-4421
Full text not available from this repository.Abstract
Rate constants have been measured for the relaxation of the a 1-DELTA-g and b 1-SIGMA-g+ states of natural O2 and O-18(2) in the liquid and gas phase up to 154 K. The ratios k(L)/k(G) of the rate constants in the liquid and gas phase at the same temperature have been determined to be between 1 and 3 for the different species. They decrease slightly with increasing temperature. The experimental values of k(L)/k(G) are compared with theoretical values calculated from the isolated binary collision model using molecules with hard or soft core.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | VIBRATIONAL-ENERGY RELAXATION; RESONANT VV TRANSFER; TEMPERATURE-DEPENDENCE; RATE CONSTANTS; 1-DELTA-G STATE; AR; ISOTOPES; CO; MIXTURES; XENON; |
| Depositing User: | Dr. Gernot Deinzer |
| Last Modified: | 19 Oct 2022 08:46 |
| URI: | https://pred.uni-regensburg.de/id/eprint/54806 |
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