BRUNNER, H and LIMMER, S (1991) ENANTIOSELECTIVE CATALYSIS .60. ADDITION OF OPTICALLY-ACTIVE AMINES TO P-SUBSTITUTED OLEFINS. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 417 (1-2). pp. 173-180. ISSN 0022-328X,
Full text not available from this repository.Abstract
The addition of the optically active amines (-)-1-phenylethylamine, (+)-1-phenylethylamine, and (+)-3-aminomethylpinane to diphenylvinylphosphine oxide or 1,1-bis(diphenylphosphino)ethene sulfide gives new PN compounds which were used as cocatalysts in the cross coupling of 1-phenylethyl Grignard with vinylbromide and in the hydrosilylation of acetophenone with diphenylsilane.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | VINYLIDENE DIPHOSPHINE COMPLEXES; NUCLEOPHILIC MICHAEL ADDITIONS; ASYMMETRIC CATALYZES; RH-COMPLEXES; (PH2P)2C=CH2; HYDROSILYLATION; PLATINUM(II); ACTIVATION; LIGANDS; CR; |
| Depositing User: | Dr. Gernot Deinzer |
| Last Modified: | 19 Oct 2022 08:46 |
| URI: | https://pred.uni-regensburg.de/id/eprint/54844 |
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