ASYMMETRIC CATALYSIS .65. ENANTIOSELECTIVE ALKYLATION OF ALPHA-ISOPROPYL-3,4-DIMETHOXYBENZYLCYANIDE

BRUNNER, H and ZINTL, H (1991) ASYMMETRIC CATALYSIS .65. ENANTIOSELECTIVE ALKYLATION OF ALPHA-ISOPROPYL-3,4-DIMETHOXYBENZYLCYANIDE. MONATSHEFTE FUR CHEMIE, 122 (10). pp. 841-848. ISSN 0026-9247,

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Abstract

The base-catalyzed Michael reaction and the palladium-catalyzed allylation were used to build up the quaternary asymmetric center of the Verapamil skeleton by enantioselective alkylation of alpha-isopropyl-3,4-dimethoxybenzylcyanide. Optical inductions up to 10.5% ee were achieved.

Item Type: Article
Uncontrolled Keywords: COMPLEXES; CINCHONA; MICHAEL REACTION; ALLYLATION; ENANTIOSELECTIVITY; PD-CATALYSIS
Depositing User: Dr. Gernot Deinzer
Last Modified: 19 Oct 2022 08:46
URI: https://pred.uni-regensburg.de/id/eprint/54847

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