BRUNNER, H and LIMMER, S (1991) ENANTIOSELECTIVE CATALYSIS .59. ADDITIONAL OF OPTICALLY-ACTIVE P-H COMPOUNDS TO P-SUBSTITUTED OLEFINS. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 413 (1-3). pp. 55-63. ISSN 0022-328X,
Full text not available from this repository.Abstract
The base-catalyzed addition of the optically active P-H phospholanes tarpholane and diopholane to olefins activated by diphenylphosphino or diphenylphosphinoyl groups gives unsymmetrical chelate phosphines which are used as cocatalysts in the hydrogenation of (Z)-alpha-N-acetamidocinnamic acid, in the cross-coupling of 1-phenylethyl Grignard with vinylbromide, and in the hydrosilylation of acetophenone with diphenylsilane.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ASYMMETRIC CATALYSIS; TARTARIC ACID; RH-COMPLEXES; PHOSPHINES; LIGANDS; HYDROSILYLATION; HYDROGENATION; BONDS; |
| Depositing User: | Dr. Gernot Deinzer |
| Last Modified: | 19 Oct 2022 08:46 |
| URI: | https://pred.uni-regensburg.de/id/eprint/54919 |
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