TEMPERATURE AND PRESSURE-DEPENDENCE OF SELF-DIFFUSION IN LONG LIQUID NORMAL-ALKANES

VARDAG, T and KARGER, N and LUDEMANN, HD (1991) TEMPERATURE AND PRESSURE-DEPENDENCE OF SELF-DIFFUSION IN LONG LIQUID NORMAL-ALKANES. BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 95 (8). pp. 859-865. ISSN 0005-9021,

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Abstract

A titanium autoclave for the determination of self diffusion coefficients by the pulsed field gradient spin-echo method is described, that has been used in the temperature range between 200 and 500 K at pressures up to 600 MPa. - In a first series of experiments, melts of n-alkanes with chain lengths between 16 and 154 carbon atoms were studied. The data are analyzed with modifications of the hard sphere model and tested against the Rouse- and reptation model.

Item Type: Article
Uncontrolled Keywords: HARD-SPHERE FLUID; TRANSPORT-COEFFICIENTS; HYDROCARBONS; DYNAMICS; WATER; NMR; DIFFUSION; HIGH PRESSURE; LIQUIDS; SPECTROSCOPY, NUCLEAR MAGNETIC RESONANCE; TRANSPORT PROPERTIES
Depositing User: Dr. Gernot Deinzer
Last Modified: 19 Oct 2022 08:46
URI: https://pred.uni-regensburg.de/id/eprint/54926

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