ASYMMETRICAL CATALYSTS .64. ENANTIOSELECTIVE EPOXIDATION OF N-ALKYL-TRICHLOROACETAMIDE WITH OPTICALLY-ACTIVE MO CATALYSTS

BRUNNER, H and ZINTL, H (1991) ASYMMETRICAL CATALYSTS .64. ENANTIOSELECTIVE EPOXIDATION OF N-ALKYL-TRICHLOROACETAMIDE WITH OPTICALLY-ACTIVE MO CATALYSTS. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 411 (3). pp. 375-382. ISSN 0022-328X,

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Abstract

In the presence of Mo(O)2(acac)2, N-allyl-trichloroacetamide was oxidized by tert-butyl hydroperoxide to give N-2,3-epoxypropyl-trichloroacetamide. Optical inductions up to 45% were achieved by using diisopropyl tartrate as ligand.

Item Type: Article
Uncontrolled Keywords: EPOXIDATION; OLEFINS; HYDROPEROXIDES;
Depositing User: Dr. Gernot Deinzer
Last Modified: 19 Oct 2022 08:46
URI: https://pred.uni-regensburg.de/id/eprint/54948

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