Quintero-Duque, Samuel and Dyballa, Katrin Marie and Fleischer, Ivana (2015) Metal-catalyzed carbonylation of alkynes: key aspects and recent development. TETRAHEDRON LETTERS, 56 (21). pp. 2634-2650. ISSN 0040-4039,
Full text not available from this repository. (Request a copy)Abstract
Carbonyl compounds represent an important class of synthetic intermediates in organic chemistry with growing industrial significance. Among the plethora of methods available for their synthesis, metal-catalyzed carbonylations constitute one of the most prominent ones, due to their efficiency, atom-economy, and often excellent selectivity. Carbonylations of alkynes give access to different types of compounds, such as unsaturated carboxylic acid derivatives or various heterocycles. Many of these products are bulk chemicals, biologically active compounds, or intermediates in the total synthesis. In recent years, considerable progress was made in this field, especially with commercial catalysts based on palladium, rhodium, and cobalt. (C) 2015 Elsevier Ltd. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | PAUSON-KHAND REACTION; CYCLIZATION COUPLING REACTION; CHELATION-ASSISTED TRANSFORMATION; PHASE-TRANSFER CONDITIONS; CHIRAL PHOSPHINE-LIGANDS; CARBON-MONOXIDE; TERMINAL ALKYNES; INTERNAL ALKYNES; ALLYL HALIDES; PALLADIUM(II)-BISOXAZOLINE CATALYST; Homogeneous catalysis; Carbonylation; Alkynes; Hydroesterification; Pauson-Khand reaction |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Dr. Ivana Fleischer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 18 Jul 2019 08:41 |
| Last Modified: | 18 Jul 2019 08:41 |
| URI: | https://pred.uni-regensburg.de/id/eprint/5495 |
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