Seitz, A. E. and Heinl, V. and Timoshkin, A. Y. and Scheer, M. (2017) Transformation of nortricyclane type cage compounds P4S3, P4Se3 and As4S3 by [Cp '' Zr-2(CO)(2)]. CHEMICAL COMMUNICATIONS, 53 (6). pp. 1172-1175. ISSN 1359-7345, 1364-548X
Full text not available from this repository. (Request a copy)Abstract
The complex [Cp"Zr-2(CO)(2)] (Cp" = C(5)H(3)tBu(2)) was used to transform the nortricyclane type cage compounds E(4)Q(3) (E = P, Q = S, Se; E = As, Q = S) resulting in unprecedented complexes [(Cp"Zr-2)(2)(mu,eta(1:1:1:1)-E(2)Q(4))] possessing bridging ligands that represent the anions of the so far unknown tetrachalcogenohypodiphosphorous acid (HQ)(2)PP(QH)(2) and tetrathiohypodiarsenous acid (HS)(2)AsAs(SH)(2), respectively.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | TRANSITION-METAL-COMPLEXES; PHOSPHORUS BOND-CLEAVAGE; RAY CRYSTAL-STRUCTURE; MAIN-GROUP ELEMENTS; DIPHOSPHORUS-SULFUR; COBALT COMPLEXES; P-4 ACTIVATION; CYCLIC UNITS; LIGANDS; CHEMISTRY; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 14 Dec 2018 13:01 |
| Last Modified: | 26 Feb 2019 07:55 |
| URI: | https://pred.uni-regensburg.de/id/eprint/550 |
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