2,4,6-TRIARYL-1,3,5-LAMBDA-3-DIAZAPHOSPHININES

Märkl, Gottfried and Dörges, Christian (1991) 2,4,6-TRIARYL-1,3,5-LAMBDA-3-DIAZAPHOSPHININES. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 30 (1). pp. 106-107. ISSN 0570-0833

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Abstract

The first 1,3,5-lambda-3-diazaphosphinines 2 were synthesized from 3,5-diazapyrylium tetrafluoroborates 1 by O/P exchange with tris(trimethylsilyl)phosphane. Compounds 2 react with alkyne dienophiles in a reaction cascade to give the highly functionalized lambda-3-phosphinines 3 (Aryl1, Aryl2 = C6H5, 4-C6H4CH3, 4-C6H4Cl; R1, R2 = H, C6H5, SiMe3, CO2Et).

Item Type: Article
Uncontrolled Keywords: 1,3-LAMBDA-3-AZAARSININES; SALTS
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie
Depositing User: Petra Gürster
Date Deposited: 02 Jul 2024 06:55
Last Modified: 02 Jul 2024 06:55
URI: https://pred.uni-regensburg.de/id/eprint/55113

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