Yao, Chang-Jiang and Sun, Qiu and Rastogi, Namrata and Koenig, Burkhard (2015) Intermolecular Formyloxyarylation of Alkenes by Photoredox Meerwein Reaction. ACS CATALYSIS, 5 (5). pp. 2935-2938. ISSN 2155-5435,
Full text not available from this repository. (Request a copy)Abstract
The intermolecular formyloxylation-arylation of stilbenes occurs in the presence of diazonium salts, a photocatalyst, visible light, and DMF. The photo-Meerwein addition products are obtained in good yields up to 76%. We propose the formation of an iminium ion intermediate, which is hydrolyzed to the product.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ARYL DIAZONIUM SALTS; METAL-FREE; C-H; ARENEDIAZONIUM SALTS; ASYMMETRIC-SYNTHESIS; ORGANIC-SYNTHESIS; LIGHT; ARYLATION; CATALYSIS; CHEMISTRY; formyloxylation-arylation; Meerwein reaction; photocatalysis; diazonium salts; N,N-dimethylformamide |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 18 Jul 2019 11:24 |
| Last Modified: | 18 Jul 2019 11:24 |
| URI: | https://pred.uni-regensburg.de/id/eprint/5554 |
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