Heindl, Claudia and Schindler, Andrea and Bodensteiner, Michael and Peresypkina, Eugenia V. and Virovets, Alexander V. and Scheer, Manfred (2015) Synthesis and Characterization of the Novel 1,2,4-Triphosphaferrocene [Cp*Fe(eta(5)-P(3)C(2)Mes(2))] Containing Sterically Demanding Mesityl Groups. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 190 (4). pp. 397-403. ISSN 1042-6507, 1563-5325
Full text not available from this repository. (Request a copy)Abstract
To vary the substitution pattern of 1,2,4-triphospholyl ligands, K[P(3)C(2)Mes(2)] (Mes=2,4,6-trimethylphenyl), bearing two bulky mesityl ligands, was synthesized. Subsequent reaction with [FeBr2(dme)] and LiCp* results in the formation of the corresponding triphosphaferrocene [Cp*Fe(eta(5)-P(3)C(2)Mes(2))] (1) in very good yields. P-31{H-1} NMR investigations reveal a temperature depending behavior of the chemical shifts of 1. The X-ray structural analysis exhibits an eclipsed sandwich compound.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | C-H ACTIVATION; MOLECULAR-STRUCTURES; TRIPHOSPHA-FERROCENES; COORDINATION CHEMISTRY; CRYSTAL-STRUCTURE; COMPLEX; LIGANDS; FE(ETA(5)-C5H5)(ETA(5)-P(3)C(2)BU(2)(T)); STABILIZATION; SYSTEMS; mesityl; Phosphorus; phospholyl; iron; triphosphaferrocene |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 22 Jul 2019 08:28 |
| Last Modified: | 22 Jul 2019 08:28 |
| URI: | https://pred.uni-regensburg.de/id/eprint/5652 |
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