Wu, Shangze and Kaur, Jaspreet and Karl, Tobias A. and Tian, Xianhai and Barham, Joshua P. (2022) Synthetic Molecular Photoelectrochemistry: New Frontiers in Synthetic Applications, Mechanistic Insights and Scalability. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 61 (12): e202107811. ISSN 1433-7851, 1521-3773
Full text not available from this repository. (Request a copy)Abstract
Synthetic photoelectrochemistry (PEC) is receiving increasing attention as a new frontier for the generation and handling of reactive intermediates. PEC permits selective single-electron transfer (SET) reactions in a much greener way and broadens the redox window of possible transformations. Herein, the most recent contributions are reviewed, demonstrating exciting new opportunities, namely, the combination of PEC with other reactivity paradigms (hydrogen-atom transfer, radical polar crossover, energy transfer sensitization), scalability up to multigram scale, novel selectivities in SET superoxidations/reductions and the importance of precomplexation to temporally enable excited radical ion catalysis.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | electrophotocatalysis; hydrogen atom transfer; photoelectrochemistry; photoredox catalysis; preassembly |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie |
| Depositing User: | Petra Gürster |
| Date Deposited: | 02 Jul 2024 06:51 |
| Last Modified: | 02 Jul 2024 06:51 |
| URI: | https://pred.uni-regensburg.de/id/eprint/56648 |
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