Barham, Joshua P. and Domansk, Michal and Zurauskas, Jonas (2022) Tunable Microwave Flow System for Scalable Synthesis of Alkyl Ionic Liquids. ORGANIC PROCESS RESEARCH & DEVELOPMENT, 26 (8). pp. 2498-2509. ISSN 1083-6160, 1520-586X
Full text not available from this repository. (Request a copy)Abstract
A continuous flow auto-frequency tuning single-mode microwave reactor is disclosed as a powerful platform to synthesize alkyl imidazolium salts as ionic liquids/ionic liquid precursors in up to near-quantitative yields, 100-600 g h(-1) productivities and record space-time yields. Challenges faced, including viscosity changes, dielectric property changes, and phase separations, were addressed by different operation modes of the reactor without reactor redesigning. Depending on the purpose, this highly productive method could prove to be useful for intensive applications of ionic liquids.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | SOLVENT-FREE SYNTHESIS; ORGANIC-SYNTHESIS; CLAISEN REARRANGEMENT; REACTOR; THERMOCHEMISTRY; IMIDAZOLIUM; EFFICIENT; OVENS; SAFE; microwave chemistry; flow chemistry; ionic liquids; imidazolium salts; microwave flow reactor; impedance matching; auto-frequency tuning |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie |
| Depositing User: | Petra Gürster |
| Date Deposited: | 12 Oct 2023 06:29 |
| Last Modified: | 29 Feb 2024 14:45 |
| URI: | https://pred.uni-regensburg.de/id/eprint/56657 |
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