Zhao, Quan-Qing and Rehbein, Julia and Reiser, Oliver (2022) Thermoneutral synthesis of spiro-1,4-cyclohexadienes by visible-light-driven dearomatization of benzylmalonates. GREEN CHEMISTRY, 24 (7). pp. 2772-2776. ISSN 1463-9262, 1463-9270
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A visible-light-driven dearomatization of unactivated arenes with perfect atom economy to access spiro-1,4-cyclohexadienes is disclosed. Calculations suggest that the overall process is approximately thermoneutral, showcasing the special opportunities of light-driven processes to develop sustainable transformations that defy thermodynamic requirements.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | PHOTOREDOX CATALYSIS; FUNCTIONALIZATION; PHOTOCATALYSIS; REACTIVITY; RADICALS; FACILE; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 05 Dec 2023 07:59 |
| Last Modified: | 05 Dec 2023 07:59 |
| URI: | https://pred.uni-regensburg.de/id/eprint/56869 |
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