Narobe, Rok and Murugesan, Kathiravan and Haag, Christoph and Schirmer, Tobias Emanuel and Koenig, Burkhard (2022) C(sp(3))-H Ritter amination by excitation of in situ generated iodine(iii)-BF3 complexes. CHEMICAL COMMUNICATIONS, 58 (63). pp. 8778-8781. ISSN 1359-7345, 1364-548X
Full text not available from this repository. (Request a copy)Abstract
Visible light excitation of iodine(iii)-BF3 complex enables the formation of carbocations from C(sp(3))-H bonds. The complexes are generated catalytically from iodoarene, carboxylate ligand, the oxidizing agent Selectfluor, and the Lewis acid BF3. This modular catalytic system allows the formation of synthetically valuable amine derivatives without a metal- or photocatalyst.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | HYDROGEN-ATOM TRANSFER; C-H AMINATION; ACTIVATION; OXIDATION; RADICALS; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 05 Dec 2023 09:57 |
| Last Modified: | 05 Dec 2023 09:57 |
| URI: | https://pred.uni-regensburg.de/id/eprint/56896 |
Actions (login required)
 |
View Item |
