Haimerl, Maria and Spitzer, Fabian and Timoshkin, Alexey Y. and Seidl, Michael and Scheer, Manfred (2022) Coordination of cage compounds by Cu(I) nacnac compounds. POLYHEDRON, 223: 115957. ISSN 0277-5387, 1873-3719
Full text not available from this repository. (Request a copy)Abstract
The nacnac Cu(I) compound [(LCu)-Cu-1(MeCN)] (L-1 = [{N(C6H3Me2-2,6)C(Me)}(2)CH](-)) was reacted with E-4 (P-4, As-4 and AsP3) yielding the homobimetallic complexes [((LCu)-Cu-1)(2)(eta(2:2)-E-4)] (E-4 = P-4 (1a), As-4 (1b), AsP3 (1c)) and the mononuclear complexes [(LCu)-Cu-1(eta(2)-E-4)] (E-4 = P-4 (2a), As-4 (2b), AsP3 (2c)), revealing neutral, intact side-on coordinated E-4 units. Furthermore, the reaction of [(LCu)-Cu-1(MeCN)] with Se-red and E4S3 (E = P, As) afforded [(LCu)(2)(mu,eta Se-2:2(2))] (L-1 = 3a, L-3 = 3b) and [((LCu)-Cu-3)(2)(E4S3)] (E = P (4), As (5)). They represent rare examples of complexes of group 11 metals with polypnictogen, chalcogen and mixed E15/Q16 compounds.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | PHOSPHORUS BOND-CLEAVAGE; CRYSTAL-STRUCTURE; COVALENT RADII; P-4 ACTIVATION; LIGAND; COMPLEXES; ELEMENTS; P4S3; REACTIVITY; MOLECULES; Yellow arsenic; White phosphorus; Nacnac; Copper; Cage compounds |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 09 Jan 2024 14:49 |
| Last Modified: | 09 Jan 2024 14:49 |
| URI: | https://pred.uni-regensburg.de/id/eprint/57135 |
Actions (login required)
 |
View Item |
